First reductive dimerization of a polycyclic azine - Archive ouverte HAL Access content directly
Journal Articles Dalton Transactions Year : 2009

First reductive dimerization of a polycyclic azine

(1) , (1) , (2) , (2) , (1)
1
2

Abstract

The tptz molecule is reduced by potassium into its anion-radical in the compound K(tptz)2 (1), whereas it is reductively coupled by SmI2 and UI3(py)4 into the bis-triazinide ligand in the dinuclear complexes [Sm2(tptz– tptz)(DMF)8][I]4·3.5DMF (2·3.5DMF) and U2I6(tptz– tptz)(MeCN)2·2MeCN (3·2MeCN) where each metal ion occupies a pentadentate N5 cavity of the [tptz–tptz]2– ligand.
Fichier principal
Vignette du fichier
berthetetal09.pdf (219.69 Ko) Télécharger le fichier
Origin : Files produced by the author(s)
Loading...

Dates and versions

hal-00492628 , version 1 (16-06-2010)

Identifiers

Cite

Jean Claude Berthet, Pierre Thuéry, Cécile Baudin, Bruno Boizot, Michel Ephritikhine. First reductive dimerization of a polycyclic azine. Dalton Transactions, 2009, 37, pp.7613. ⟨10.1039/b909547k⟩. ⟨hal-00492628⟩
120 View
690 Download

Altmetric

Share

Gmail Facebook Twitter LinkedIn More