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Journal articles
First reductive dimerization of a polycyclic azine
Abstract : The tptz molecule is reduced by potassium into its anion-radical in the compound K(tptz)2 (1), whereas it is reductively coupled by SmI2 and UI3(py)4 into the bis-triazinide ligand in the dinuclear complexes [Sm2(tptz– tptz)(DMF)8][I]4·3.5DMF (2·3.5DMF) and U2I6(tptz– tptz)(MeCN)2·2MeCN (3·2MeCN) where each metal ion occupies a pentadentate N5 cavity of the [tptz–tptz]2– ligand.
Cited literature [5 references]
https://hal-polytechnique.archives-ouvertes.fr/hal-00492628
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Submitted on : Wednesday, June 16, 2010 - 3:26:08 PM
Last modification on : Friday, March 5, 2021 - 2:59:14 PM
Long-term archiving on: : Friday, September 17, 2010 - 1:50:23 PM
Contributor : Boizot Bruno Connect in order to contact the contributor
Submitted on : Wednesday, June 16, 2010 - 3:26:08 PM
Last modification on : Friday, March 5, 2021 - 2:59:14 PM
Long-term archiving on: : Friday, September 17, 2010 - 1:50:23 PM
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