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Conference papers
Synthesis of powellite-rich glasses for high level waste immobilization
Abstract : Increasing amounts of MoO3 were added to SiO2-B2O3-Na2O-CaO-Al2O3 glasses in order to trap molybdenum as powellite (nominally CaMoO4). Different heat treatments were performed to study their influences on powellite crystallization by X-ray diffraction and EPR. The glass compositions studied in this work lead to glass-ceramics rich in CaMoO4, up to [MoO3] = 5 mol% no poorly durable Na2MoO4 phase was identified by XRD. Trivalent actinides surrogates (Gd3+) were observed to incorporate into CaMoO4 crystals.
Cited literature [5 references]
https://hal-polytechnique.archives-ouvertes.fr/hal-00599090
Contributor : Boizot Bruno <>
Submitted on : Wednesday, June 8, 2011 - 2:24:16 PM
Last modification on : Friday, March 5, 2021 - 3:06:11 PM
Long-term archiving on: : Friday, September 9, 2011 - 12:05:36 PM
Contributor : Boizot Bruno <>
Submitted on : Wednesday, June 8, 2011 - 2:24:16 PM
Last modification on : Friday, March 5, 2021 - 3:06:11 PM
Long-term archiving on: : Friday, September 9, 2011 - 12:05:36 PM
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