Chirped molecular vibration in a stilbene derivative in solution

Abstract : The wave packet dynamics of 4-methoxy-4'-nitrostilbene in solution was studied by femtosecond pump-probe spectroscopy. Transient changes in absorbance exhibit oscillations, which reflect vibrational motions on the ground-state potential surface. Modification of this oscillatory feature in three different solvents (benzene, methanol, and acetonitrile) can be explained in term of the strength of hydrogen bonding and the stabilization of charge-transfer state, confirmed by steady-state absorption and fluorescence spectra. Cop. 2007 Elsevier B.V. All rights reserved.
Document type :
Journal articles
Complete list of metadatas

https://hal-polytechnique.archives-ouvertes.fr/hal-00821498
Contributor : Denis Roura <>
Submitted on : Friday, May 17, 2013 - 10:07:24 PM
Last modification on : Thursday, June 13, 2019 - 8:56:02 PM

Identifiers

Collections

Citation

Anne Colonna, A. Yabushita, I. Iwakura, T. Kobayashi. Chirped molecular vibration in a stilbene derivative in solution. Chemical Physics, Elsevier, 2007, 341 (40969), pp.336. ⟨10.1016/j.chemphys.2007.08.028⟩. ⟨hal-00821498⟩

Share

Metrics

Record views

143