Wavelength dependence of nonlinear circular dichroism in a chiral ruthenium-tris(bipyridyl) solution

H. Mesnil 1 Marie-Claire Schanne-Klein 1 François Hache 1, * M. Alexandre 2 G. Lemercier 2 Chantal Andraud 2
* Corresponding author
1 LOB - Laboratoire d'optique et biosciences
2 STIM - Stéréochimie et Interactions Moléculaires
Abstract : Nonlinear circular dichroism is studied in a solution of ruthenium-tris(bipyridyl) salt in one-beam and pump-probe experiments by tuning the laser wavelength across the circular dichroism structure. The dispersion of the nonlinear circular dichroism is measured. This wavelength dependence is well accounted for by a model calculation where nonlocality is included in the optical response of a two-coupled-oscillator system. This calculation also allows us to address the question of the contribution of electric quadrupolarization to the nonlinear optical activity of an isotropic liquid of chiral molecules. © 2002 The American Physical Society
Document type :
Journal articles
Complete list of metadatas
https://hal-polytechnique.archives-ouvertes.fr/hal-00837032
Contributor : Denis Roura <>
Submitted on : Monday, May 19, 2014 - 1:56:33 PM
Last modification on : Thursday, January 16, 2020 - 10:10:14 AM
Long-term archiving on: Wednesday, April 5, 2017 - 1:56:51 AM

File

PhysRevA.66.013802.pdf
Publisher files allowed on an open archive

Identifiers

Collections

CNRS | X-LOB | ENS-LYON | X | PARISTECH | UNIV-LYON1 | X-DEP-BIO | UDL

Citation

H. Mesnil, Marie-Claire Schanne-Klein, François Hache, M. Alexandre, G. Lemercier, et al.. Wavelength dependence of nonlinear circular dichroism in a chiral ruthenium-tris(bipyridyl) solution. Physical Review A, American Physical Society, 2002, 66 (1), pp.138021. ⟨10.1103/PhysRevA.66.013802⟩. ⟨hal-00837032⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Record views

366

Files downloads

458

Contact

Informations

CCSD