Abstract : A homobimetallic complex, [{Sm(tta)3(MeOH)}2(μ-bpm)]*1 bpm (tta = 2-thenoyltrifluoroacetonato, bpm = 2,2′-bipyrimidine) has been synthesized and structurally characterized by single-crystal X-ray diffraction. Magnetic measurements (between 5 and 295 K) show that the two metal centers bridged by the bpm connector are magnetically almost isolated. The SmIII emission is observed upon excitation in a wide range of wavelengths going from the UV to the visible (250-500 nm).
https://hal-polytechnique.archives-ouvertes.fr/hal-00906189
Contributor : Francoise Girard
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Submitted on : Tuesday, November 19, 2013 - 1:48:51 PM
Last modification on : Tuesday, July 30, 2019 - 8:26:05 AM
