Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle. - Archive ouverte HAL Access content directly
Journal Articles Chemical Communications Year : 2012

Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle.

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Frédéric La Paglia
  • Function : Author
Dušan Sredojević
  • Function : Author
Michel Pfeffer
Jean-Pierre Djukic

Abstract

A chromiumtricarbonyl-bound iridacycle displays novel catalytic virtues for the conversion of terminal aromatic alkynes into racemic N-phenyl, 1-arylethylamines by tandem hydro-amination and hydrosilation/protodesilation reactions under mild "one pot" conditions.
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Dates and versions

hal-00906193 , version 1 (19-11-2013)

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Cite

Wissam Iali, Frédéric La Paglia, X. F Le Goff, Dušan Sredojević, Michel Pfeffer, et al.. Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle.. Chemical Communications, 2012, 48 (83), pp.10310-2. ⟨10.1039/c2cc35520e⟩. ⟨hal-00906193⟩
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