Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle.

Abstract : A chromiumtricarbonyl-bound iridacycle displays novel catalytic virtues for the conversion of terminal aromatic alkynes into racemic N-phenyl, 1-arylethylamines by tandem hydro-amination and hydrosilation/protodesilation reactions under mild "one pot" conditions.
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Submitted on : Tuesday, November 19, 2013 - 1:55:29 PM
Last modification on : Tuesday, July 30, 2019 - 8:26:06 AM

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Wissam Iali, Frédéric La Paglia, Xavier-Frédéric Le Goff, Dušan Sredojević, Michel Pfeffer, et al.. Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle.. Chemical Communications, Royal Society of Chemistry, 2012, 48 (83), pp.10310-2. ⟨10.1039/c2cc35520e⟩. ⟨hal-00906193⟩

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