Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle.

Wissam Iali (1) , Frédéric La Paglia , X. F Le Goff (2) , Dušan Sredojević , Michel Pfeffer (3) , Jean-Pierre Djukic (3)

1 Institut de Chimie de Strasbourg
2 DCPH - Laboratoire Hétéroéléments et Coordination
3 Institut de Chimie de Strasbourg

A chromiumtricarbonyl-bound iridacycle displays novel catalytic virtues for the conversion of terminal aromatic alkynes into racemic N-phenyl, 1-arylethylamines by tandem hydro-amination and hydrosilation/protodesilation reactions under mild "one pot" conditions.

Domains: Chemical Sciences; Coordination chemistry

Wissam Iali, Frédéric La Paglia, X. F Le Goff, Dušan Sredojević, Michel Pfeffer, et al.. Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle.. Chemical Communications, 2012, 48 (83), pp.10310-2. ⟨10.1039/c2cc35520e⟩. ⟨hal-00906193⟩