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Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle.

Wissam Iali 1 Frédéric La Paglia X. Le Goff 2 Dušan Sredojević Michel Pfeffer 3 Jean-Pierre Djukic 3
1 Institut de Chimie de Strasbourg
2 DCPH - Laboratoire Hétéroéléments et Coordination
3 Institut de Chimie de Strasbourg
Abstract : A chromiumtricarbonyl-bound iridacycle displays novel catalytic virtues for the conversion of terminal aromatic alkynes into racemic N-phenyl, 1-arylethylamines by tandem hydro-amination and hydrosilation/protodesilation reactions under mild "one pot" conditions.
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https://hal-polytechnique.archives-ouvertes.fr/hal-00906193
Contributor : Francoise Girard <>
Submitted on : Tuesday, November 19, 2013 - 1:55:29 PM
Last modification on : Sunday, January 3, 2021 - 7:54:02 PM

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CNRS | X | X-DCPH | INC-CNRS | SITE-ALSACE | X-DEP-CHIM

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Wissam Iali, Frédéric La Paglia, X. Le Goff, Dušan Sredojević, Michel Pfeffer, et al.. Room temperature tandem hydroamination and hydrosilation/protodesilation catalysis by a tricarbonylchromium-bound iridacycle.. Chemical Communications, Royal Society of Chemistry, 2012, 48 (83), pp.10310-2. ⟨10.1039/c2cc35520e⟩. ⟨hal-00906193⟩

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