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Journal articles
Synthesis of Phosphorus(V)-Stabilized Geminal Dianions. The Cases of Mixed P=X/P?BH3 (X = S, O) and P=S/SiMe3 Derivatives
Abstract : The monodeprotonation of [CH2(PPh2→BH3)(PPh2═E)] (E = S (6), O (7)) afforded [CH(PPh2→BH3)(PPh2═E)]− (E = S (6-), O (7-)), whose structures were confirmed by X-ray crystallography. The kinetics of the second deprotonation appeared to be crucial in efficient synthesis of the corresponding dianions. Thus, the double deprotonation of 6 only led to 62-; the analogous reaction with 7 was slower and resulted only in the partial formation of 72-. Double deprotonation of the compound [CH2(SiMe3)(PPh2═S)] (8) also resulted in the partial formation of [C(SiMe3)(PPh2═S)]2- (82-), whose structure was confirmed by X-ray crystallography. The rare monomeric Mg carbene compound [MgC(PPh2→BH3)(PPh2═S)] (9) was obtained by the reaction of 6 with Mg(nBu)2. The X-ray structure of 9 is presented.
https://hal-polytechnique.archives-ouvertes.fr/hal-00906704
Contributor : Francoise Girard <>
Submitted on : Wednesday, November 20, 2013 - 11:14:41 AM
Last modification on : Wednesday, November 18, 2020 - 2:42:04 PM
Contributor : Francoise Girard <>
Submitted on : Wednesday, November 20, 2013 - 11:14:41 AM
Last modification on : Wednesday, November 18, 2020 - 2:42:04 PM