 |
École polytechnique Open archive |  |
 |
Journal articles
Gas-phase basicity of formaldehyde by the thermokinetic method
Abstract : A series of proton transfer reactions monitored in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer allows the determination of the gas-phase basicity (GB) and the proton affinity (PA) of formaldehyde. The values determined by the thermokinetic method, GB(CH2O) = 681.5 ± 0.7 kJ mol-1 and PA(CH2O) = 711.5 ± 2.1 kJ mol-1 are in excellent agreement with data originating from proton transfer equilibrium constant determinations or from G2 calculations.
https://hal-polytechnique.archives-ouvertes.fr/hal-00922248
Contributor : Denis Roura <>
Submitted on : Wednesday, December 25, 2013 - 2:36:36 PM
Last modification on : Thursday, March 5, 2020 - 6:21:48 PM
Contributor : Denis Roura <>
Submitted on : Wednesday, December 25, 2013 - 2:36:36 PM
Last modification on : Thursday, March 5, 2020 - 6:21:48 PM