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Journal articles
Gas-phase basicity of formaldehyde by the thermokinetic method
Abstract : A series of proton transfer reactions monitored in a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer allows the determination of the gas-phase basicity (GB) and the proton affinity (PA) of formaldehyde. The values determined by the thermokinetic method, GB(CH2O) = 681.5 ± 0.7 kJ mol-1 and PA(CH2O) = 711.5 ± 2.1 kJ mol-1 are in excellent agreement with data originating from proton transfer equilibrium constant determinations or from G2 calculations.
https://hal-polytechnique.archives-ouvertes.fr/hal-00922248
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Wednesday, December 25, 2013 - 2:36:36 PM
Last modification on : Wednesday, December 15, 2021 - 10:00:42 AM
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Wednesday, December 25, 2013 - 2:36:36 PM
Last modification on : Wednesday, December 15, 2021 - 10:00:42 AM