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Abstract : We report the first total synthesis of flossonol in only five steps and of one of its isomers in seven steps using a radical addition/cyclization sequence as the key step. Comparison of our spectroscopic data with those of the literature indicates a misassignment in the structure of flossonol.
https://hal-polytechnique.archives-ouvertes.fr/hal-00949975 Contributor : Denis RouraConnect in order to contact the contributor Submitted on : Monday, February 24, 2014 - 5:32:05 PM Last modification on : Thursday, December 9, 2021 - 2:26:02 PM
Raphael F. Guignard. A Concise Total Synthesis of the Purported Structure of Flossonol. SYNLETT, Georg Thieme Verlag, 2013, 24 (2), pp.157-160. ⟨10.1055/s-0032-1317848⟩. ⟨hal-00949975⟩