Expedient approach to novel N-unprotected bicyclic azapyrimidine and pyridine structures.

Abstract : A direct route to novel bicyclic N-unprotected azapyrimidine structures including fused five-, six-, and seven-membered rings is described involving radical addition and cyclization of xanthates; this approach could be partially extended to pyridines.
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Zhibo Liu, Ling Qin, Samir Zard. Expedient approach to novel N-unprotected bicyclic azapyrimidine and pyridine structures.. Organic Letters, American Chemical Society, 2012, 14 (23), pp.5976-5979. ⟨10.1021/ol3028829⟩. ⟨hal-00949984⟩

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