Palladium-catalyzed ring opening of aminocyclopropyl Ugi adducts

Abstract : The ring opening of aminocyclopropanes triggered by activation with an intramolecular arylpalladium(II) iodide complex is an interesting strategy for the synthesis of nitrogen heterocycles and a valuable Ugi postcondensation-type transformation. Six- and seven-membered-ring cyclic enamines may be obtained. © Georg Thieme Verlag Stuttgart * New York.
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Aurélie dos Santos, Laurent El Kaim, Laurence Grimaud, Romain Ramozzi. Palladium-catalyzed ring opening of aminocyclopropyl Ugi adducts. SYNLETT, Georg Thieme Verlag, 2012, pp.438-442. ⟨10.1055/s-0031-1290312⟩. ⟨hal-00949987⟩

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