Rapid assembly of polycyclic structures via sigmatropic rearrangement of s-propargyl xanthates

Abstract : Upon heating in chlorobenzene, propargyl xanthates yield the corresponding 4,5-bis(alkylidene)-1,3-dithiolan-2-ones which are trapped by unactivated olefins in an intramolecular Diels-Alder cycloaddition yielding interesting polycyclic structures.
Document type :
Journal articles
Complete list of metadatas

Cited literature [2 references]  Display  Hide  Download

https://hal-polytechnique.archives-ouvertes.fr/hal-00949988
Contributor : Denis Roura <>
Submitted on : Tuesday, April 29, 2014 - 2:15:00 PM
Last modification on : Thursday, February 7, 2019 - 4:28:47 PM
Long-term archiving on: Tuesday, July 29, 2014 - 10:50:20 AM

File

COM-12-S_N_98.pdf
Files produced by the author(s)

Identifiers

Collections

Citation

Ryan M. Harrington, David Wright, Samir Zard. Rapid assembly of polycyclic structures via sigmatropic rearrangement of s-propargyl xanthates. Heterocycles, The Japan Institute of Heterocyclic Chemistry, 2012, 86 (2), pp.965-971. ⟨10.3987/com-12-s(n)98⟩. ⟨hal-00949988⟩

Share

Metrics

Record views

204

Files downloads

255