A flexible, unified radical-based approach to polycyclic structures

Rama Heng (1) , Samir Z. Zard (1)

1 DCSO - Laboratoire de synthèse organique

Cis- and trans-decalins, trans-perhydroazulenes, and [5.3.1]-bicyclo- undecanone scaffolds can be readily constructed starting from unsaturated ketones and using the degenerative xanthate transfer technology to accomplish unusual and otherwise difficult radical cyclisations. © 2011 The Royal Society of Chemistry.

Domaines: Chimie organique

Rama Heng, Samir Z. Zard. A flexible, unified radical-based approach to polycyclic structures. Organic & Biomolecular Chemistry, 2011, 9 (9), pp.3396-3404. ⟨10.1039/c1ob00024a⟩. ⟨hal-00950007⟩