Formation of cinnoline derivatives by a gold(I)-catalyzed hydroarylation of N-propargyl-N'-arylhydrazines

Abstract : A study concerning the gold(I)-catalyzed hydroarylation of N-propargyl-N'-arylhydrazinecarboxylic acid methyl esters is described. The use of the gold complex [XPhosAu(NCCH3)SbF6] as the catalyst in refluxing nitromethane allows the generally rapid and efficient synthesis of a range of functionalized 4-exo-methylene-1,2-dihydrocinnolines. © 2010 Elsevier B.V. All rights reserved.
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Igor Jurberg, Fabien Gagosz. Formation of cinnoline derivatives by a gold(I)-catalyzed hydroarylation of N-propargyl-N'-arylhydrazines. Journal of Organometallic Chemistry, Elsevier, 2011, 696 (1), pp.37-41. ⟨10.1016/j.jorganchem.2010.06.017⟩. ⟨hal-00950023⟩

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