Gold and brønsted acid catalyzed hydride shift onto allenes: Divergence in product selectivity

Abstract : A series of allenyl ethers can be transformed into various fused or spiro tetrahydrofurans and tetrahydropyrans following a hydride shift/cyclization sequence. A divergence in product selectivity, which depends on the nature of the catalyst used (Au(I) complex or Brønsted acid), was observed. © 2011 American Chemical Society.
Document type :
Journal articles
Complete list of metadatas

https://hal-polytechnique.archives-ouvertes.fr/hal-00950025
Contributor : Denis Roura <>
Submitted on : Wednesday, February 26, 2014 - 8:45:35 PM
Last modification on : Thursday, February 7, 2019 - 5:19:35 PM

Identifiers

Collections

Citation

Benoit Bolte, Fabien Gagosz. Gold and brønsted acid catalyzed hydride shift onto allenes: Divergence in product selectivity. Journal of the American Chemical Society, American Chemical Society, 2011, 133 (20), pp.7696-7699. ⟨10.1021/ja202336p⟩. ⟨hal-00950025⟩

Share

Metrics

Record views

133