Gold(i)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates

Abstract : The use of [XPhosAu(NCMe)]SbF6 in nitromethane at 100 °C allows the rapid and efficient formation of variously substituted dihydroquinolines, which can be subsequently converted into indoles by a rare photochemical rearrangement. © 2011 The Royal Society of Chemistry.
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Colombe Gronnier, Yann Odabachian, Fabien Gagosz. Gold(i)-catalyzed formation of dihydroquinolines and indoles from N-aminophenyl propargyl malonates. Chemical Communications, Royal Society of Chemistry, 2011, 47 (1), pp.218-220. ⟨10.1039/c0cc00033g⟩. ⟨hal-00950026⟩

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