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Highly demanding cross-metathesis in the synthesis of the C16-C30 fragment of dolabelide C
Abstract : A highly demanding cross-metathesis (CM) reaction for the formation of the C24-C25 trisubstituted olefin of dolabelide C has been optimized. A difference in reactivity between the E and Z enone isomers in this reaction was uncovered, and the selection of the Z isomer of the starting enone was critical for the success of the cross-metathesis. Application to the synthesis of the C16-C30 fragment of dolabelide C is reported. © 2011 American Chemical Society.
https://hal-polytechnique.archives-ouvertes.fr/hal-00951226
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Wednesday, February 26, 2014 - 9:06:35 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Wednesday, February 26, 2014 - 9:06:35 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM