 |
École polytechnique Open archive |  |
 |
Journal articles
Highly demanding cross-metathesis in the synthesis of the C16-C30 fragment of dolabelide C
Abstract : A highly demanding cross-metathesis (CM) reaction for the formation of the C24-C25 trisubstituted olefin of dolabelide C has been optimized. A difference in reactivity between the E and Z enone isomers in this reaction was uncovered, and the selection of the Z isomer of the starting enone was critical for the success of the cross-metathesis. Application to the synthesis of the C16-C30 fragment of dolabelide C is reported. © 2011 American Chemical Society.
https://hal-polytechnique.archives-ouvertes.fr/hal-00951226
Contributor : Denis Roura <>
Submitted on : Wednesday, February 26, 2014 - 9:06:35 PM
Last modification on : Tuesday, December 8, 2020 - 1:46:01 PM
Contributor : Denis Roura <>
Submitted on : Wednesday, February 26, 2014 - 9:06:35 PM
Last modification on : Tuesday, December 8, 2020 - 1:46:01 PM