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Journal articles
Modular approach to saturated and a,ß-unsaturated ketones
Abstract : 2-Fluoro-6-pyridinyloxy derivatives of 2-ethoxyvinyl carbinols react with radicals derived from xanthates by an addition-fragmentation pathway to give highly functionalized ketones after acid hydrolysis. 1,4-Diketones are readily accessible by this approach. a,ß-Unsaturated ketones can be obtained by starting with geminal acetoxy xanthates prepared by addition of a simpler xanthate to vinyl acetate. © 2011 American Chemical Society.
https://hal-polytechnique.archives-ouvertes.fr/hal-00951228
Contributor : Denis Roura <>
Submitted on : Wednesday, February 26, 2014 - 9:16:19 PM
Last modification on : Thursday, March 5, 2020 - 6:25:21 PM
Contributor : Denis Roura <>
Submitted on : Wednesday, February 26, 2014 - 9:16:19 PM
Last modification on : Thursday, March 5, 2020 - 6:25:21 PM