Service interruption on Monday 11 July from 12:30 to 13:00: all the sites of the CCSD (HAL, EpiSciences, SciencesConf, AureHAL) will be inaccessible (network hardware connection).
Skip to Main content Skip to Navigation
Journal articles

Modular approach to saturated and a,ß-unsaturated ketones

Abstract : 2-Fluoro-6-pyridinyloxy derivatives of 2-ethoxyvinyl carbinols react with radicals derived from xanthates by an addition-fragmentation pathway to give highly functionalized ketones after acid hydrolysis. 1,4-Diketones are readily accessible by this approach. a,ß-Unsaturated ketones can be obtained by starting with geminal acetoxy xanthates prepared by addition of a simpler xanthate to vinyl acetate. © 2011 American Chemical Society.
Document type :
Journal articles
Complete list of metadata

https://hal-polytechnique.archives-ouvertes.fr/hal-00951228
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Wednesday, February 26, 2014 - 9:16:19 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM

Identifiers

Collections

Citation

Laurent Debien, Béatrice Quiclet-Sire, Samir Z. Zard. Modular approach to saturated and a,ß-unsaturated ketones. Organic Letters, American Chemical Society, 2011, 13 (20), pp.5676-5679. ⟨10.1021/ol202399c⟩. ⟨hal-00951228⟩

Share

Metrics

Record views

123