Transfer of Chirality by the Use of an All Carbon Tether

Marie-Gabrielle Braun (1) , Rama Heng (1) , Samir Z. Zard (1)

1 DCSO - Laboratoire de synthèse organique

Methylketone side chains can be used to direct the creation of one or more chiral centers, including quaternary centers, by exploiting the ability of the radical xanthate transfer process to mediate six-membered ring formation.(Figure Presented) © 2011 American Chemical Society.

Domaines: Chimie organique

Marie-Gabrielle Braun, Rama Heng, Samir Z. Zard. Transfer of Chirality by the Use of an All Carbon Tether. Organic Letters, 2011, 13 (5), pp.1230-1233. ⟨10.1021/ol2001182⟩. ⟨hal-00951235⟩