Unusual radical addition on a heteroaromatic nitrogen. A convenient access to new pyrimidine derivatives

Abstract : A radical generated on the side-chain of a 2- or 4-N-alkylamino-4,6- or 2,6-dichloropyrimidine can cyclise on the nitrogen or on the carbon of the pyrimidine ring depending on its position and on whether an acetyl or a Boc group is present on the extra-nuclear nitrogen. © 2010 The Royal Society of Chemistry.
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Yann Laot, Laurent Petit, Samir Zard. Unusual radical addition on a heteroaromatic nitrogen. A convenient access to new pyrimidine derivatives. Chemical Communications, Royal Society of Chemistry, 2010, 46 (31), pp.5784-5786. ⟨10.1039/c0cc00533a⟩. ⟨hal-00951258⟩

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