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Journal Articles Organic Letters Year : 2009

A flexible radical-based approach to tms-substituted propargyl alcohols and to 2,3-allenols

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Abstract

The radical reaction of TMS-substituted xanthates with 2,2-dlchlorovlnyl ethyl sulfone afforded TMS-substltuted homodichlorovinyl compounds that can be transformed Into TMS-substituted propargyl alcohols. Various 2,3-allenols were efficiently prepared from the reaction of these TMS-substituted propargyl alcohols with TBAF. © 2009 American Chemical Society.
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hal-00951260 , version 1 (28-02-2014)

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Zhi Li, Samir Z. Zard. A flexible radical-based approach to tms-substituted propargyl alcohols and to 2,3-allenols. Organic Letters, 2009, 11 (13), pp.2868-2871. ⟨10.1021/ol900739x⟩. ⟨hal-00951260⟩
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