A flexible radical-based approach to tms-substituted propargyl alcohols and to 2,3-allenols

Zhi Li 1 Samir Zard 1, *
* Corresponding author
1 DCSO - Laboratoire de synthèse organique
Abstract : The radical reaction of TMS-substituted xanthates with 2,2-dlchlorovlnyl ethyl sulfone afforded TMS-substltuted homodichlorovinyl compounds that can be transformed Into TMS-substituted propargyl alcohols. Various 2,3-allenols were efficiently prepared from the reaction of these TMS-substituted propargyl alcohols with TBAF. © 2009 American Chemical Society.
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Submitted on : Friday, February 28, 2014 - 8:54:47 PM
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Zhi Li, Samir Zard. A flexible radical-based approach to tms-substituted propargyl alcohols and to 2,3-allenols. Organic Letters, American Chemical Society, 2009, 11 (13), pp.2868-2871. ⟨10.1021/ol900739x⟩. ⟨hal-00951260⟩

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