A versatile radical based approach to O-alkylated hydroxylamines and oximes

Béatrice Quiclet-Sire; Daniel Woollaston; Samir Zard

doi:10.1016/j.tet.2008.08.113

Journal articles

A versatile radical based approach to O-alkylated hydroxylamines and oximes

Béatrice Quiclet-Sire ¹ Daniel Woollaston ¹ Samir Zard ^{1, *}

* Corresponding author

1 DCSO - Laboratoire de synthèse organique

Abstract : O-Alkylhydroxylamines, often used for the preparation of bioconjugates, can be readily obtained by radical addition to suitable O-alkenylhydroxylamine derivatives. In the case of N-Boc-O-allylhydroxylamine, the addition is unexpectedly followed by elimination resulting in an overall allylation of the radical species. © 2008 Elsevier Ltd. All rights reserved.

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Journal articles

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Chemical Sciences / Organic chemistry

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A versatile radical based approach to O-alkylated hydroxylamines and oximes

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A versatile radical based approach to O-alkylated hydroxylamines and oximes

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