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Journal Articles Tetrahedron Year : 2008

A versatile radical based approach to O-alkylated hydroxylamines and oximes

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Abstract

O-Alkylhydroxylamines, often used for the preparation of bioconjugates, can be readily obtained by radical addition to suitable O-alkenylhydroxylamine derivatives. In the case of N-Boc-O-allylhydroxylamine, the addition is unexpectedly followed by elimination resulting in an overall allylation of the radical species. © 2008 Elsevier Ltd. All rights reserved.

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hal-00951273 , version 1 (03-03-2014)

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Béatrice Quiclet-Sire, Daniel Woollaston, Samir Z. Zard. A versatile radical based approach to O-alkylated hydroxylamines and oximes. Tetrahedron, 2008, 64 (52), pp.11917-11924. ⟨10.1016/j.tet.2008.08.113⟩. ⟨hal-00951273⟩
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