Gold(I)-catalyzed [4+2] annelation/nucleophilic addition sequence: stereoselective synthesis of functionalized bicyclo[4.3.0]nonenes

Sébastien Böhringer 1 Fabien Gagosz 1, *
* Corresponding author
1 DCSO - Laboratoire de synthèse organique
Abstract : The gold(I)-catalyzed isomerization of readily available 1,8-dien-4-ynes allows the rapid construction of a variety of synthetically useful bicyclo[4.3.0]nonenes by a stereoselective sequence involving a [4+2] annelation/nucleophilic addition process. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
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Submitted on : Monday, March 3, 2014 - 2:12:10 PM
Last modification on : Thursday, February 7, 2019 - 4:59:14 PM

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Sébastien Böhringer, Fabien Gagosz. Gold(I)-catalyzed [4+2] annelation/nucleophilic addition sequence: stereoselective synthesis of functionalized bicyclo[4.3.0]nonenes. Advanced Synthesis and Catalysis, Wiley-VCH Verlag, 2008, 350 (16), pp.2617-2630. ⟨10.1002/adsc.200800413⟩. ⟨hal-00951275⟩

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