Gold(I)-catalyzed [4+2] annelation/nucleophilic addition sequence: stereoselective synthesis of functionalized bicyclo[4.3.0]nonenes

Sébastien Böhringer; Fabien Gagosz

doi:10.1002/adsc.200800413

Journal articles

Gold(I)-catalyzed [4+2] annelation/nucleophilic addition sequence: stereoselective synthesis of functionalized bicyclo[4.3.0]nonenes

Sébastien Böhringer ¹ Fabien Gagosz ^{1, *}

* Corresponding author

1 DCSO - Laboratoire de synthèse organique

Abstract : The gold(I)-catalyzed isomerization of readily available 1,8-dien-4-ynes allows the rapid construction of a variety of synthetically useful bicyclo[4.3.0]nonenes by a stereoselective sequence involving a [4+2] annelation/nucleophilic addition process. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

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Gold(I)-catalyzed [4+2] annelation/nucleophilic addition sequence: stereoselective synthesis of functionalized bicyclo[4.3.0]nonenes

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Gold(I)-catalyzed [4+2] annelation/nucleophilic addition sequence: stereoselective synthesis of functionalized bicyclo[4.3.0]nonenes

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