Gold(I)-catalyzed [4+2] annelation/nucleophilic addition sequence: stereoselective synthesis of functionalized bicyclo[4.3.0]nonenes

Sébastien Böhringer (1) , Fabien Gagosz (1)

1 DCSO - Laboratoire de synthèse organique

The gold(I)-catalyzed isomerization of readily available 1,8-dien-4-ynes allows the rapid construction of a variety of synthetically useful bicyclo[4.3.0]nonenes by a stereoselective sequence involving a [4+2] annelation/nucleophilic addition process. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Sébastien Böhringer, Fabien Gagosz. Gold(I)-catalyzed [4+2] annelation/nucleophilic addition sequence: stereoselective synthesis of functionalized bicyclo[4.3.0]nonenes. Advanced Synthesis and Catalysis, 2008, 350 (16), pp.2617-2630. ⟨10.1002/adsc.200800413⟩. ⟨hal-00951275⟩