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Radical allylation with a-branched allyl sulfones
Abstract : (Chemical Equation Presented) Branching out with sulfones: The use of allyl isopropyl sulfones solves the problem of premature isomerization and allows the radical addition of xanthates to a-branched allyl sulfones (see scheme; DCE=1,2-dichloroethane, TMS=trimethylsilyl). Highly functionalized structures can thus be rapidly assembled under mild reaction conditions by using cheap and readily available substrates and reagents. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
https://hal-polytechnique.archives-ouvertes.fr/hal-00951276
Contributor : Denis Roura <>
Submitted on : Monday, March 3, 2014 - 2:14:32 PM
Last modification on : Thursday, March 5, 2020 - 6:25:22 PM
Contributor : Denis Roura <>
Submitted on : Monday, March 3, 2014 - 2:14:32 PM
Last modification on : Thursday, March 5, 2020 - 6:25:22 PM
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