An unexpected synthesis of ketene monothioacetals

Stéphanie Fabre (1) , Xavier Vila (1) , Samir Z. Zard (1)

1 DCSO - Laboratoire de synthèse organique

Some dithiocarbonates (xanthates) can be converted into ketene monothioacetals through extrusion of sulfur upon treatment with base and an alkylating agent. © The Royal Society of Chemistry.

Domaines: Chimie organique

Stéphanie Fabre, Xavier Vila, Samir Z. Zard. An unexpected synthesis of ketene monothioacetals. Chemical Communications, 2006, 47, pp.4964-4966. ⟨10.1039/b612336h⟩. ⟨hal-00951305⟩