Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent

Sharanjee Bagal 1 Michiel de Greef 1 Samir Zard 1, *
* Corresponding author
1 DCSO - Laboratoire de synthèse organique
Abstract : (Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study. © 2006 American Chemical Society.
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Submitted on : Monday, March 3, 2014 - 3:00:13 PM
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Sharanjee Bagal, Michiel de Greef, Samir Zard. Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent. Organic Letters, American Chemical Society, 2006, 8 (1), pp.147-150. ⟨10.1021/ol052634m⟩. ⟨hal-00951307⟩

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