Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent

Sharanjee Bagal 1 Michiel de Greef 1 Samir Zard 1, *
* Corresponding author
1 DCSO - Laboratoire de synthèse organique
Abstract : (Chemical Equation Presented) Cyano(ethoxycarbonothioylthio)methyl benzoate 3 has been prepared and shown to be an excellent one-carbon radical equivalent that can be applied for the introduction of an acyl unit via xanthate transfer radical addition to olefins. The corresponding adducts can be further elaborated. A rare 1,5-nitrile translocation was also observed during the study. © 2006 American Chemical Society.
Document type :
Journal articles
Complete list of metadatas
https://hal-polytechnique.archives-ouvertes.fr/hal-00951307
Contributor : Denis Roura <>
Submitted on : Monday, March 3, 2014 - 3:00:13 PM
Last modification on : Thursday, February 7, 2019 - 5:16:40 PM

Identifiers

Collections

X-DCSO | X | PARISTECH | INC-CNRS | X-DEP-CHIM

Citation

Sharanjee Bagal, Michiel de Greef, Samir Zard. Cyano(ethoxycarbonothioylthio)methyl benzoate: A novel one-carbon radical equivalent. Organic Letters, American Chemical Society, 2006, 8 (1), pp.147-150. ⟨10.1021/ol052634m⟩. ⟨hal-00951307⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Record views

100

Contact

support.ccsd.cnrs.fr
hal.support@ccsd.cnrs.fr
Logo CCSD