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Radical additions of xanthates to vinyl epoxides and related derivatives: A powerful tool for the modular creation of quaternary centers
Abstract : (Chemical Equation Presented) An open relationship: The triethylborane/O2-mediated addition of xanthates to vinyl epoxides and derivatives represents an efficient process to form carbon-carbon bonds. Complex structures can be rapidly assembled in a modular, convergent manner, under mild conditions, using readily available reagents (see scheme, Bn = benzyl). The formation of quaternary centers proved especially facile. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
https://hal-polytechnique.archives-ouvertes.fr/hal-00954778
Contributor : Denis Roura <>
Submitted on : Monday, March 24, 2014 - 8:47:28 PM
Last modification on : Thursday, March 5, 2020 - 6:25:45 PM
Contributor : Denis Roura <>
Submitted on : Monday, March 24, 2014 - 8:47:28 PM
Last modification on : Thursday, March 5, 2020 - 6:25:45 PM
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