Radicals from aldehydes: A convergent access to dienes and d-lactones

Sharanjeet Bagal 1 Lucie Tournier 1 Samir Zard 1
1 DCSO - Laboratoire de synthèse organique
Abstract : A convenient method for the generation of O,S-acetal xanthates from aldehydes has been developed. The corresponding nucleophilic radicals undergo facile addition to unactivated olefins and the resulting adducts can be further elaborated to generate dienes and unsaturated d-lactones. © Georg Thieme Verlag Stuttgart.
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Submitted on : Monday, March 24, 2014 - 8:45:48 PM
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Sharanjeet Bagal, Lucie Tournier, Samir Zard. Radicals from aldehydes: A convergent access to dienes and d-lactones. SYNLETT, Georg Thieme Verlag, 2006, pp.1485-1490. ⟨10.1055/s-2006-941582⟩. ⟨hal-00954779⟩

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