Substituted allyl diphenylphosphine oxides as radical allylating agents

Gilles Ouvry 1 Béatrice Quiclet-Sire 1 Samir Zard 1
1 DCSO - Laboratoire de synthèse organique
Abstract : (Chemical Equation Presented) Radically useful: The radical addition of dithiocarbonates to branched allyl diphenylphosphine oxides can be followed by elimination of a diphenylphosphinoyl radical, thereby giving rise to allylated products (see scheme; Phth = phthalimido). Highly functionalized structures can thus be rapidly assembled under mild conditions and from cheap and readily available substrates and reagents. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Document type :
Journal articles
Complete list of metadatas
https://hal-polytechnique.archives-ouvertes.fr/hal-00954781
Contributor : Denis Roura <>
Submitted on : Monday, March 24, 2014 - 8:42:08 PM
Last modification on : Thursday, February 7, 2019 - 5:09:56 PM

Links full text

istex

Identifiers

Collections

CNRS | X-DCSO | X | PARISTECH | INC-CNRS | X-DEP-CHIM

Citation

Gilles Ouvry, Béatrice Quiclet-Sire, Samir Zard. Substituted allyl diphenylphosphine oxides as radical allylating agents. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2006, 45 (30), pp.5002-5006. ⟨10.1002/anie.200601556⟩. ⟨hal-00954781⟩

Export

BibTeX TEI DC DCterms EndNote

Share

Metrics

Record views

122

Contact

Informations

CCSD