Substituted allyl diphenylphosphine oxides as radical allylating agents

Abstract : (Chemical Equation Presented) Radically useful: The radical addition of dithiocarbonates to branched allyl diphenylphosphine oxides can be followed by elimination of a diphenylphosphinoyl radical, thereby giving rise to allylated products (see scheme; Phth = phthalimido). Highly functionalized structures can thus be rapidly assembled under mild conditions and from cheap and readily available substrates and reagents. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
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Gilles Ouvry, Béatrice Quiclet-Sire, Samir Zard. Substituted allyl diphenylphosphine oxides as radical allylating agents. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2006, 45 (30), pp.5002-5006. ⟨10.1002/anie.200601556⟩. ⟨hal-00954781⟩

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