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The genesis of the reversible radical addition-fragmentation-transfer of thiocarbonylthio derivatives from the Barton-McCombie deoxygenation: A brief account and some mechanistic observations
Abstract : The observations and reasoning leading to the discovery of the degenerative transfer of xanthates and related thiocarbonylthio derivatives are briefly described. A few synthetic applications are presented, and the consequences on the emergence of the RAFT and MADIX polymerization technologies as well as some mechanistic aspects are briefly discussed. © CSIRO 2006.
https://hal-polytechnique.archives-ouvertes.fr/hal-00954784
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Monday, March 24, 2014 - 5:32:43 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Monday, March 24, 2014 - 5:32:43 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM