A direct approach to a-hydroxy and a-chloro trifluoromethyl derivatives

Abstract : S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2-trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide. S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2- trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide. © 2004 Elsevier Ltd. All rights reserved.
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Lucie Tournier, Samir Zard. A direct approach to a-hydroxy and a-chloro trifluoromethyl derivatives. Tetrahedron Letters, Elsevier, 2005, 46 (3), pp.455-459. ⟨10.1016/j.tetlet.2004.11.086⟩. ⟨hal-00954801⟩

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