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A practical variation on the Leuckart reaction

Abstract : S-Aryldiazo xanthates, derived from the corresponding diazonium salts by reaction with potassium O-ethyl xanthate, undergo a radical chain reaction with loss of nitrogen; the intermediate aromatic radical can be captured by an internal olefin to give bicyclic xanthates in good overall yield. © 2004 Elsevier Ltd. All rights reserved.
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Submitted on : Monday, March 24, 2014 - 5:20:45 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM

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Lucie Tournier, Samir Z. Zard. A practical variation on the Leuckart reaction. Tetrahedron Letters, Elsevier, 2005, 46 (6), pp.971-973. ⟨10.1016/j.tetlet.2004.12.042⟩. ⟨hal-00954802⟩

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