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Journal Articles Tetrahedron Letters Year : 2005

A practical variation on the Leuckart reaction

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Abstract

S-Aryldiazo xanthates, derived from the corresponding diazonium salts by reaction with potassium O-ethyl xanthate, undergo a radical chain reaction with loss of nitrogen; the intermediate aromatic radical can be captured by an internal olefin to give bicyclic xanthates in good overall yield. © 2004 Elsevier Ltd. All rights reserved.

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hal-00954802 , version 1 (24-03-2014)

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Lucie Tournier, Samir Z. Zard. A practical variation on the Leuckart reaction. Tetrahedron Letters, 2005, 46 (6), pp.971-973. ⟨10.1016/j.tetlet.2004.12.042⟩. ⟨hal-00954802⟩
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