Generation and ring opening of aziridine N-carbonyl radicals

Marcus R. Heinrich (1, 2) , Inès Pérez-Martín (2) , Samir Z. Zard (2)

1 Organische Chemie 1
2 DCSO - Laboratoire de synthèse organique

Aziridine N-carbonyl radicals, generated by irradiating the corresponding S-oxalyl xanthates, undergo ring opening to give 2-isocyanato radicals, which can be trapped by an external olefin. © The Royal Society of Chemistry 2005.

Domaines: Chimie organique

Marcus R. Heinrich, Inès Pérez-Martín, Samir Z. Zard. Generation and ring opening of aziridine N-carbonyl radicals. Chemical Communications, 2005, 47, pp.5928-5930. ⟨10.1039/b512956g⟩. ⟨hal-00954804⟩