Generation and ring opening of aziridine N-carbonyl radicals

Abstract : Aziridine N-carbonyl radicals, generated by irradiating the corresponding S-oxalyl xanthates, undergo ring opening to give 2-isocyanato radicals, which can be trapped by an external olefin. © The Royal Society of Chemistry 2005.
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Marcus Heinrich, Inès Pérez-Martín, Samir Zard. Generation and ring opening of aziridine N-carbonyl radicals. Chemical Communications, Royal Society of Chemistry, 2005, pp.5928-5930. ⟨10.1039/b512956g⟩. ⟨hal-00954804⟩

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