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A new, practical access to amidyl radicals

Abstract : Amidyl radicals are readily generated from N-allylsulfonimides by the action of a xanthate and a small amount of a peroxide as initiator. The process involves extrusion of sulfur dioxide from an N-amidosulfonyl radical by rupture of the nitrogen-sulfur bond; in some cases, the N-amidosulfonyl radical is prematurely captured by the internal olefinic trap.
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Submitted on : Monday, March 24, 2014 - 1:46:52 PM
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Cécille Moutrille, Samir Z. Zard. A new, practical access to amidyl radicals. Chemical Communications, 2004, 16, pp.1848-1849. ⟨10.1039/b405545d⟩. ⟨hal-00954814⟩



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