A direct approach to a-trifluoromethylamines

Abstract : (Matrix presented) S-[1-(N-Acetylamino)-2,2,2-trifluoroethyl]-O-ethyl dithiocarbonate (6), a readily available xanthate, adds efficiently to various functionalized olefins to give the corresponding adducts 8 via a radical chain reaction initiated by a small amount of lauroyl peroxide.
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Fabien Gagosz, Samir Zard. A direct approach to a-trifluoromethylamines. Organic Letters, American Chemical Society, 2003, 5 (15), pp.2655-2657. ⟨10.1021/ol034812m⟩. ⟨hal-00954822⟩

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