A new, unexpected synthesis of 1,3-dithietanones

Abstract : Treatment of a geminal pivaloxy xanthate, prepared by an intermolecular radical addition of a xanthate to vinyl pivalate, gives a 1,3-dithietanone, a little known class of compounds.
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Béatrice Quiclet-Sire, Graciela Sanchez-Jimenez, Samir Zard. A new, unexpected synthesis of 1,3-dithietanones. Chemical Communications, Royal Society of Chemistry, 2003, 9 (12), pp.1408-1409. ⟨10.1039/B302434B⟩. ⟨hal-00954823⟩

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