Amidinyl radicals: New and useful intermediates for the synthesis of imidazolines and imidazoles

Dominique Gennet 1 Samir Zard 1 Haiwen Zhang 1
1 DCSO - Laboratoire de synthèse organique
Abstract : Amidinyl radicals are readily generated from amidoxime benzoates by treatment with a stannane-diazo initiator or with Ni-AcOH and captured by an internal olefin to give the corresponding imidazoline.
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Submitted on : Monday, March 24, 2014 - 12:59:41 PM
Last modification on : Thursday, February 7, 2019 - 4:42:23 PM

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Dominique Gennet, Samir Zard, Haiwen Zhang. Amidinyl radicals: New and useful intermediates for the synthesis of imidazolines and imidazoles. Chemical Communications, Royal Society of Chemistry, 2003, 9 (15), pp.1870-1871. ⟨10.1039/B304545E⟩. ⟨hal-00954827⟩

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