Convergent access to ketones, vinyl esters and vinyl bromides by a tin-free radical addition-intramolecular hydrogen atom transfer

Abstract : Xanthate-mediated intermolecular radical addition, hydrogen atom transfer and sulfonyl radical elimination have been efficiently combined in a new convergent synthesis of ketones and substituted olefins.
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Gilles Ouvry, Samir Zard. Convergent access to ketones, vinyl esters and vinyl bromides by a tin-free radical addition-intramolecular hydrogen atom transfer. Chemical Communications, Royal Society of Chemistry, 2003, 9 (6), pp.778-779. ⟨10.1039/B212841A⟩. ⟨hal-00954828⟩

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