Convergent access to ketones, vinyl esters and vinyl bromides by a tin-free radical addition-intramolecular hydrogen atom transfer

Gilles Ouvry (1) , Samir Z. Zard (1)

1 DCSO - Laboratoire de synthèse organique

Xanthate-mediated intermolecular radical addition, hydrogen atom transfer and sulfonyl radical elimination have been efficiently combined in a new convergent synthesis of ketones and substituted olefins.

Gilles Ouvry, Samir Z. Zard. Convergent access to ketones, vinyl esters and vinyl bromides by a tin-free radical addition-intramolecular hydrogen atom transfer. Chemical Communications, 2003, 9 (6), pp.778-779. ⟨10.1039/B212841A⟩. ⟨hal-00954828⟩