Intermolecular additions of cyclobutanone derived radicals. A convergent, highly efficient access to polycyclic cyclobutane containing structures

Grégori Binot; Samir Zard

doi:10.1016/j.tetlet.2003.09.042

Journal articles

Intermolecular additions of cyclobutanone derived radicals. A convergent, highly efficient access to polycyclic cyclobutane containing structures

Grégori Binot ¹ Samir Zard ^{1, *}

* Corresponding author

1 DCSO - Laboratoire de synthèse organique

Abstract : a-Xanthyl cyclobutanones undergo intermolecular radical additions to olefins bearing various functional groups. Adducts containing a phosphonate can be made to cyclise by an internal Wittig-Horner-Emmons reaction to give cyclohexene and cycloheptene rings fused to the cyclobutane. © 2003 Elsevier Ltd. All rights reserved.

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Intermolecular additions of cyclobutanone derived radicals. A convergent, highly efficient access to polycyclic cyclobutane containing structures

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Intermolecular additions of cyclobutanone derived radicals. A convergent, highly efficient access to polycyclic cyclobutane containing structures

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