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A convergent, flexible synthesis of 1,3-dienes

Abstract : 1,3-Dienes were prepared from 1,4-ketoxanthates, obtained by the radical addition reaction of an S-(2-oxoalkyl) xanthate to a terminal olefin, through the DBU induced thermal elimination of sulfur dioxide from the derived 2-sulfolenes.
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Submitted on : Tuesday, March 18, 2014 - 9:11:04 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM

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Marie Lusinchi, Trevor Stanbury, Samir Zard. A convergent, flexible synthesis of 1,3-dienes. Chemical Communications, Royal Society of Chemistry, 2002, pp.1532-1533. ⟨10.1039/B203975C⟩. ⟨hal-00954838⟩



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