A convergent, flexible synthesis of 1,3-dienes

Marie Lusinchi (1) , Trevor V. Stanbury (1) , Samir Z. Zard (1)

1 DCSO - Laboratoire de synthèse organique

1,3-Dienes were prepared from 1,4-ketoxanthates, obtained by the radical addition reaction of an S-(2-oxoalkyl) xanthate to a terminal olefin, through the DBU induced thermal elimination of sulfur dioxide from the derived 2-sulfolenes.

Domains: Chemical Sciences; Organic chemistry

Marie Lusinchi, Trevor V. Stanbury, Samir Z. Zard. A convergent, flexible synthesis of 1,3-dienes. Chemical Communications, 2002, 14, pp.1532-1533. ⟨10.1039/B203975C⟩. ⟨hal-00954838⟩