A new tin-free source of amidyl radicals

Abstract : (Matrix presented) The readily available N-(O-ethyl thiocarbonylsulfanyl)amides are powerful amidyl radical precursors that undergo 5-exo cyclization to give pyrrolidinone derivatives via a radical-chain reaction initiated by a small amount of lauroyl peroxide.
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Submitted on : Tuesday, March 18, 2014 - 8:48:45 PM
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Fabien Gagosz, Cécille Moutrille, Samir Zard. A new tin-free source of amidyl radicals. Organic Letters, American Chemical Society, 2002, 4 (16), pp.2707-2709. ⟨10.1021/ol026221m⟩. ⟨hal-00954848⟩

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