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A short synthesis of (±)-13-deoxyserratine
Abstract : A short and efficient total synthesis of (±)-13-deoxyserratine (3) features a highly stereoselective intramolecular Pauson-Khand reaction of 1 and a cascade of radical cyclizations starting with the amidyl radical 2. The desired alkaloid 3 was thus obtained in ten steps in an overall yield of 12 %. THP = tetrahydropyranyl, TBS = tert-butyldimethylsilyl.
https://hal-polytechnique.archives-ouvertes.fr/hal-00954852
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Tuesday, March 18, 2014 - 8:36:37 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM
Contributor : Denis Roura Connect in order to contact the contributor
Submitted on : Tuesday, March 18, 2014 - 8:36:37 PM
Last modification on : Thursday, December 9, 2021 - 2:26:02 PM
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