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Journal articles
Synthesis of protected syn 1,3-diols by intramolecular conjugate addition to vinyl sulfones
Abstract : A short route to sulfones 9a-c is described. These synthons encompassing a syn 1,3-diol motif are model compounds for the C16-C24 fragment of Dolabelides. The benzylidene protecting group can be reduced regioselectively to furnish ß-hydroxysulfones 10a-b. First attempts of Julia coupling of the dianions derived from these substrates with aldehydes and ketones are also reported. © 2002 Elsevier Science Ltd. All rights reserved.
https://hal-polytechnique.archives-ouvertes.fr/hal-00954862
Contributor : Denis Roura <>
Submitted on : Monday, March 17, 2014 - 9:22:39 PM
Last modification on : Thursday, March 5, 2020 - 6:25:47 PM
Contributor : Denis Roura <>
Submitted on : Monday, March 17, 2014 - 9:22:39 PM
Last modification on : Thursday, March 5, 2020 - 6:25:47 PM