A short and efficient synthesis of (+)-calystegine B2

F.-D. Boyer (1) , Issam Hanna (2)

1 Unité de Phytopharmacie et Médiateurs Chimiques
2 DCSO - Laboratoire de synthèse organique

A short synthesis of (+)-calystegine B2 from (D)-glucose has been achieved, which involves as the key step a triple domino zinc-mediated reductive ring-opening, imine formation and allylation reaction of 6-iodoglucopyranose. © 2001 Elsevier Science Ltd.

Mots clés: SYNTHESE

Domaines: Ingénierie des aliments; Génie des procédés

F.-D. Boyer, Issam Hanna. A short and efficient synthesis of (+)-calystegine B2. Tetrahedron Letters, 2001, 42 (7), pp.1275-1277. ⟨10.1016/S0040-4039(00)02262-0⟩. ⟨hal-00954870⟩