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A new approach to cyclohexenes and related structures

Abstract : Intermolecular radical addition of a xanthyl phosphonoacetate to a ?,d-enone gives rise to an adduct suitable for a base induced Horner-Emmons ring closure to a cyclohexene derivative, optionally after the reductive removal of the xanthate group.
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Submitted on : Tuesday, March 11, 2014 - 1:51:04 PM
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N. Cholleton, Isabelle Gauthier-Gillaizeau, Yvan Six, Samir Zard. A new approach to cyclohexenes and related structures. Chemical Communications, Royal Society of Chemistry, 2000, pp.535-536. ⟨10.1039/B001119N⟩. ⟨hal-00954889⟩



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