An expedient construction of seven-membered rings adjoining aromatic systems

Abstract : An unusual radical-mediated fusion of a seven-membered ring onto an aromatic system exploits the relatively long lifetime of radicals generated using dithiocarbonares (xanthates). This type of annelation (an example is shown), which was hitherto very difficult to accomplish by more traditional radical methods, was used to construct a variety of complex structures. Y = OAc, CN, (CH2)8OAc, CH2CO2Et, phthaloyl.
Type de document :
Article dans une revue
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2000, 39 (4), pp.731-733. 〈10.1002/(SICI)1521-3773(20000218)39:4<731::AID-ANIE731>3.0.CO;2-U〉
Liste complète des métadonnées

https://hal-polytechnique.archives-ouvertes.fr/hal-00954900
Contributeur : Denis Roura <>
Soumis le : mardi 11 mars 2014 - 13:40:48
Dernière modification le : mercredi 25 avril 2018 - 10:45:12

Lien texte intégral

Identifiants

Collections

Citation

T. Kaoudi, Béatrice Quiclet-Sire, S. Seguin, Samir Zard. An expedient construction of seven-membered rings adjoining aromatic systems. Angewandte Chemie International Edition, Wiley-VCH Verlag, 2000, 39 (4), pp.731-733. 〈10.1002/(SICI)1521-3773(20000218)39:4<731::AID-ANIE731>3.0.CO;2-U〉. 〈hal-00954900〉

Partager

Métriques

Consultations de la notice

120