Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents

M. Destarac 1 D. Charmot 1 X. Franck 2 Samir Zard 3
1 Rhodia Recherches
2 ICSN - Institut de Chimie des Substances Naturelles
3 DCSO - Laboratoire de synthèse organique
Abstract : Control of the radical polymerization of acrylates, styrene and vinyl acetate has been achieved by using novel dithiocarbamates as reversible addition-fragmentation chain transfer agents. The key parameter for the control with N,N-disubstituted (A) or cyclic (B) dithiocarbamates was found to be the conjugation of the lone pair of electrons of the nitrogen atom with carbonyl or aromatic groups. © WILEY-VCH Verlag GmbH 2000.
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M. Destarac, D. Charmot, X. Franck, Samir Zard. Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents. Macromolecular Rapid Communications, Wiley-VCH Verlag, 2000, 21 (15), pp.1035-1039. ⟨10.1002/1521-3927(20001001)21:15<1035::AID-MARC1035>3.0.CO;2-5⟩. ⟨hal-00954901⟩

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