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Dithiocarbamates as universal reversible addition-fragmentation chain transfer agents
Abstract : Control of the radical polymerization of acrylates, styrene and vinyl acetate has been achieved by using novel dithiocarbamates as reversible addition-fragmentation chain transfer agents. The key parameter for the control with N,N-disubstituted (A) or cyclic (B) dithiocarbamates was found to be the conjugation of the lone pair of electrons of the nitrogen atom with carbonyl or aromatic groups. © WILEY-VCH Verlag GmbH 2000.
https://hal-polytechnique.archives-ouvertes.fr/hal-00954901
Contributor : Denis Roura <>
Submitted on : Tuesday, March 11, 2014 - 1:36:58 PM
Last modification on : Wednesday, April 7, 2021 - 2:56:05 PM
Contributor : Denis Roura <>
Submitted on : Tuesday, March 11, 2014 - 1:36:58 PM
Last modification on : Wednesday, April 7, 2021 - 2:56:05 PM
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