Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship

Abstract : A new series of xanthate MADIX agents bearing a-amido trifluoromethyl leaving R groups and exhibiting a good ability for fragmentation is kinetically investigated. Quantitative measurements of both Ctr for xanthates and Cex faithfully supported the experimental observations for Mn and PDIs.
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Submitted on : Tuesday, March 25, 2014 - 4:56:22 PM
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Mathias Destarac, Juliette Ruchmann, Xavier Vila, Samir Zard, E. Van Gramberen, et al.. Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship. 5th Controlled/living Radical Polymerization Symposium, The 236th ACS National Meeting, Aug 2008, Philadelphia, United States. pp.POLY 323. ⟨hal-00965844⟩

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