Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship

Mathias Destarac; Juliette Ruchmann; Xavier Vila; Samir Zard; E. van Gramberen; Daniel Taton

Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship

Mathias Destarac ¹ Juliette Ruchmann ² Xavier Vila ³ Samir Zard ³ E. van Gramberen ² Daniel Taton ⁴

1 LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée

2 Centre de Recherches et Technologies d'Aubervilliers

3 DCSO - Laboratoire de synthèse organique

4 LCPO - Laboratoire de Chimie des polymères organiques

Abstract : A new series of xanthate MADIX agents bearing a-amido trifluoromethyl leaving R groups and exhibiting a good ability for fragmentation is kinetically investigated. Quantitative measurements of both Ctr for xanthates and Cex faithfully supported the experimental observations for Mn and PDIs.

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Conference papers

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https://hal-polytechnique.archives-ouvertes.fr/hal-00965844
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Submitted on : Tuesday, March 25, 2014 - 4:56:22 PM
Last modification on : Monday, April 29, 2019 - 4:48:16 PM

Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship

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Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship

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