Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship

Abstract : A new series of xanthate MADIX agents bearing a-amido trifluoromethyl leaving R groups and exhibiting a good ability for fragmentation is kinetically investigated. Quantitative measurements of both Ctr for xanthates and Cex faithfully supported the experimental observations for Mn and PDIs.
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Communication dans un congrès
5th Controlled/living Radical Polymerization Symposium, The 236th ACS National Meeting, Aug 2008, Philadelphia, United States. pp.POLY 323
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https://hal-polytechnique.archives-ouvertes.fr/hal-00965844
Contributeur : Denis Roura <>
Soumis le : mardi 25 mars 2014 - 16:56:22
Dernière modification le : mardi 11 septembre 2018 - 15:18:20

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  • HAL Id : hal-00965844, version 1

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Mathias Destarac, Juliette Ruchmann, Xavier Vila, Samir Zard, E. Van Gramberen, et al.. Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship. 5th Controlled/living Radical Polymerization Symposium, The 236th ACS National Meeting, Aug 2008, Philadelphia, United States. pp.POLY 323. 〈hal-00965844〉

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