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Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship

Mathias Destarac 1 Juliette Ruchmann 2 Xavier Vila 3 Samir Zard 3 E. van Gramberen 2 Daniel Taton 4
1 LHFA - Laboratoire Hétérochimie Fondamentale et Appliquée
2 Centre de Recherches et Technologies d'Aubervilliers
3 DCSO - Laboratoire de synthèse organique
4 LCPO - Laboratoire de Chimie des polymères organiques
Abstract : A new series of xanthate MADIX agents bearing a-amido trifluoromethyl leaving R groups and exhibiting a good ability for fragmentation is kinetically investigated. Quantitative measurements of both Ctr for xanthates and Cex faithfully supported the experimental observations for Mn and PDIs.
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Conference papers
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https://hal-polytechnique.archives-ouvertes.fr/hal-00965844
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Submitted on : Tuesday, March 25, 2014 - 4:56:22 PM
Last modification on : Wednesday, December 15, 2021 - 11:18:11 AM

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  • HAL Id : hal-00965844, version 1

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CNRS | UNIV-BORDEAUX | X | X-DCSO | INC-CNRS | X-DEP-CHIM | UNIV-TLSE3 | LCPO

Citation

Mathias Destarac, Juliette Ruchmann, Xavier Vila, Samir Zard, E. van Gramberen, et al.. Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship. 5th Controlled/living Radical Polymerization Symposium, The 236th ACS National Meeting, Aug 2008, Philadelphia, United States. pp.POLY 323. ⟨hal-00965844⟩

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