Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship

Mathias Destarac 1 Juliette Ruchmann 2 Xavier Vila 3 Samir Zard 3 E. Van Gramberen 2 Daniel Taton 4
1 HFA - Hétérochimie fondamentale et appliquée
2 Centre de Recherches et Technologies d'Aubervilliers
3 DCSO - Laboratoire de synthèse organique
4 LCPO - Laboratoire de Chimie des polymères organiques
Abstract : A new series of xanthate MADIX agents bearing a-amido trifluoromethyl leaving R groups and exhibiting a good ability for fragmentation is kinetically investigated. Quantitative measurements of both Ctr for xanthates and Cex faithfully supported the experimental observations for Mn and PDIs.
Type de document :
Communication dans un congrès
5th Controlled/living Radical Polymerization Symposium, The 236th ACS National Meeting, Aug 2008, Philadelphia, United States. pp.POLY 323
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https://hal-polytechnique.archives-ouvertes.fr/hal-00965844
Contributeur : Denis Roura <>
Soumis le : mardi 25 mars 2014 - 16:56:22
Dernière modification le : mardi 11 septembre 2018 - 15:18:20

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  • HAL Id : hal-00965844, version 1

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Mathias Destarac, Juliette Ruchmann, Xavier Vila, Samir Zard, E. Van Gramberen, et al.. Kinetic behavior of a-amido trifluoromethyl xanthate Madix agents: Structure-reactivity relationship. 5th Controlled/living Radical Polymerization Symposium, The 236th ACS National Meeting, Aug 2008, Philadelphia, United States. pp.POLY 323. 〈hal-00965844〉

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