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Conference papers
Vinylogous dithiocompounds for RAFT polymerization
Abstract : The present communication focuses on a novel range of dithioester agents for reversible addition fragmentation transfer polymerization (RAFT), comprising one given (ethoxycarbonyl)ethyl leaving group and an unsaturated, potentially substituted Z group. RAFT polymerization of styrene and ethyl acrylate was efficiently conducted using four original vinylogous dithio compounds. Controlled Mn with low Mw/Mn were obtained for most of the reported experiments. The peculiar addition-fragmentation mechanism of this class of RAFT agents caused a severe retardation during polymerization.
https://hal-polytechnique.archives-ouvertes.fr/hal-00965886
Contributor : Denis Roura <>
Submitted on : Tuesday, March 25, 2014 - 5:21:02 PM
Last modification on : Wednesday, April 7, 2021 - 2:56:07 PM
Contributor : Denis Roura <>
Submitted on : Tuesday, March 25, 2014 - 5:21:02 PM
Last modification on : Wednesday, April 7, 2021 - 2:56:07 PM